Russian journal of organic chemistry

New route of reaction between acyl isothiocyanates and cyclic β-diketones

MV Vovk, NG Chubaruk, AV Bol'but

Index: Vovk; Chubaruk; Bol'but Russian Journal of Organic Chemistry, 2004 , vol. 40, # 2 p. 280 - 281

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Abstract

The reaction of acyl isothiocyanates with b-dicarbonyl compounds is thoroughly studied nowadays [1-10]. In a wide range of reaction conditions the process proceeds as C- thiocarbamoylation of the dicarbonyl component. For instance, C-thiocarbamoylated derivatives of 1, 3-cyclohexanedione [7] or dimedone [8, 9] formed in good yields at boiling reagents in dioxane or acetone. We found reaction conditions where the character of the ...

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