Phosphorus, Sulfur, and Silicon

Syntheses of the optically active terpene hydroxyphenylselenides

J Ścianowski, M Wełniak

Index: Scianowski, Jacek; WeLniak, MirosLaw Phosphorus, Sulfur and Silicon and the Related Elements, 2009 , vol. 184, # 6 p. 1440 - 1447

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Citation Number: 4

Abstract

The optically active hydroxyphenylselenides derived from the p-menthane, carane, and pinane systems have been obtained. Two methods of hydroxyphenylselenides synthesis have been compared. The first method is based on the reaction of alkenes with N- (phenylseleno) succinimide in the presence of water, and the second from epoxides as a result of the reaction with sodium benzeneselenolate. The influence of the substrate ...