Pentacoordinate Silicon Derivatives. III. 1 2, 2'2'-Nitrilotriphenol, a New Chelating Agent

CL Frye, GA Vincent, GL Hauschildt

Index: Frye,C.L. et al. Journal of the American Chemical Society, 1966 , vol. 88, p. 2727 - 2730

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Citation Number: 51

Abstract

Abstract: The copper-catalyzed condensation of 2-substituted iodobenzenes with 2- substituted anilines yielded the novel 2, 2', 2”-trichloro-, trimethyl-, and trimethoxytriphenylamines. Cleavage of the trimethoxy species produced 2, 2', 2”- nitrilotriphenol which was shown to be an effective chelating agent, reacting with a variety of silanes (ZSiX3) to form monomeric pentacoordinate derivatives, ZSi (OC6H4), N; related ...