Identification and Quantification of Defect Structures in Poly (2, 5-thienylene vinylene) Derivatives Prepared via the Dithiocarbamate Precursor Route by Means of …

…, S Chambon, TJ Cleij, L Lutsen, D Vanderzande…

Index: Dilien; Chambon; Cleij; Lutsen; Vanderzande; Adriaensens Macromolecules, 2011 , vol. 44, # 12 p. 4711 - 4720

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Abstract

During the past decades several synthetic routes toward the low band gap polymer poly (2, 5-thienylene vinylene)(PTV) and derivatives have been studied. This study describes an extensive NMR characterization of 13C-labeled 3-octyl-PTV and its precursor polymer prepared via the dithiocarbamate route which is, since stable monomers are available, a promising route toward PTV derivatives. By introducing 13C-labeled vinylene carbons, we ...

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