Pd-catalyzed C-arylation of unsaturated compounds with pentavalent triarylantimony dicarboxylates

DV Moiseev, AV Gushchin, AS Shavirin…

Index: Moiseev, Dmitry V.; Gushchin, Aleksey V.; Shavirin, Andrey S.; Kursky, Yury A.; Dodonov, Viktor A. Journal of Organometallic Chemistry, 2003 , vol. 667, # 1-2 p. 176 - 184

Full Text: HTML

Citation Number: 33

Abstract

Triarylantimony (V) derivatives Ar3SbX2 (X= Hal or acyloxy) were prepared by reaction of Ar3Sb with equimolar amounts of a peroxide ROOH (R= t-Bu, H) in the presence of an acid or an anhydride in good to excellent yields. Ar3Sb (O2CR) 2 are mild and efficient C- arylation reagents of unsaturated compounds (methyl acrylate, styrene, 2-phenylpropene and acrylonitrile) under palladium catalysis at 50° C, with PdCl2 being the most effective ...

Related Articles:

H40-PCL-PEG unimolecular micelles both as anchoring sites for palladium nanoparticles and micellar catalyst for Heck reaction in water

[Nabid, Mohammad Reza; Bide, Yasamin Applied Catalysis A: General, 2014 , vol. 469, p. 183 - 190]

H40-PCL-PEG unimolecular micelles both as anchoring sites for palladium nanoparticles and micellar catalyst for Heck reaction in water

[Nabid, Mohammad Reza; Bide, Yasamin Applied Catalysis A: General, 2014 , vol. 469, p. 183 - 190]

Mizoroki–Heck coupling reactions of arenediazonium tetrafluoroborate salts catalyzed by aluminium hydroxide-supported palladium nanoparticles

[Li, Xing; Wang, Li-Chao; Chang, Hong-Hong; Zhang, Cong-Xia; Wei, Wen-Long Applied Catalysis A: General, 2013 , vol. 462-463, p. 15 - 22]

Pd (II)-catalyzed oxidative Heck-type reaction of triarylphosphines with alkenes via carbon–phosphorus bond cleavage

[Ma, Ming-Tao; Lu, Jian-Mei Tetrahedron, 2013 , vol. 69, # 9 p. 2102 - 2106]

Pd nanoparticles immobilized on PAMAM-grafted MWCNTs hybrid materials as new recyclable catalyst for Mizoraki–Heck cross-coupling reactions

[Nabid, Mohammad Reza; Bide, Yasamin; Tabatabaei Rezaei, Seyed Jamal Applied Catalysis A: General, 2011 , vol. 406, # 1-2 p. 124 - 132]

More Articles...