Journal of organometallic chemistry

The investigation of a transsilylation reaction for the preparation of silyl esters: reactivity correlated with 29 Si NMR resonance frequencies

JM Weinberg, KL Wooley

Index: Weinberg, Jennifer M.; Wooley, Karen L. Journal of Organometallic Chemistry, 1997 , vol. 542, # 2 p. 235 - 240

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Citation Number: 15

Abstract

The investigation of a transesterification reaction involving silicon exchange (transsilylation) between a silyl ester and a chlorosilane is reported. The reaction studied involves an equilibrium interchange between trimethylsilyl benzoate and several chlorosilanes, as a preparation of various silyl esters and trimethylsilyl chloride as a volatile by-product. An interesting reactivity balance was observed, in which the reaction with some of the ...

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