Synthesis of isoquinolines by intramolecular aza-Wittig reaction

DMB Hickey, AR MacKenzie, CJ Moody…

Index: Hickey, Deirdre M. B.; MacKenzie, A. Roderick; Moody, Christopher J.; Rees, Charles W. Journal of the Chemical Society, Chemical Communications, 1984 , # 12 p. 776 - 777

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Abstract

Isoquinolines (3) and (5) are formed under miled neutral conditions by intramolecular aza- Wittig reactions of iminophospranes, readily derived from azides (1) and (4) with trithyl phosphite, the azafluranthene (7) can also be prepared from the isolable iminophosphoranes (8),(9), and (10).

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