Base catalysed rearrangement of 2-methyl-3, 3-bisalkylthioacrylophenones to 2-alkylthiomethyl-3-alkylthioacrylophenones via mobile keto allyl intermediates
S Apparao, A Rahman, H Ila, H Junjappa
Index: Apparao, S.; Rahman, A.; Ila, H.; Junjappa, H. Tetrahedron Letters, 1982 , vol. 23, # 9 p. 971 - 974 Title/Abstract Full Text View citing articles Show Details Apparao, Satyam; Ila, Hiriyakkanavar; Junjappa, Hirijakkanavar Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 12 p. 2837 - 2844
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Citation Number: 9
Abstract
Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The title compounds ( - ) undergo facile base catalysed rearrangement to give - . A mechanism involving thioallylic rearrangement of intermediates, 2-bisalkylthiomethyl acrylophenones, ( - ) has been proposed. ... 2 -S-CH 3 ); 7.04 ; 7.25–7.53 (m,5H,arom).