Palladium-mediated cycloaddition approach to cyclopentanoids. Introduction and initial studies
BM Trost, DMT Chan
Index: Trost,B.M.; Chan,D.M. Journal of the American Chemical Society, 1983 , vol. 105, p. 2315
Full Text: HTML
Citation Number: 180
Abstract
Abstract:(2-(Acetoxymethyl)-3-allyl) trimethylsilane, available from methallyl alcohol, serves as an equivalent of trimethylenemethane in cycloadditions to electron-deficient olefins. a, P- Unsaturated ketones, esters, nitriles, sulfones, and lactones serve as acceptors with this silane in the presence of a palladium (0) catalyst. Preformed (Ph3P) 4Pd or in situ reduction of palladium acetate or trifluoroacetate serves as such a catalyst. In addition to the acetate, ...
Related Articles:
[Trost,B.M.; Renaut,P. Journal of the American Chemical Society, 1982 , vol. 104, p. 6668]