Reversible exchange of (. eta. 5-cyclopentadienyl)(dinitrosoalkane) cobalt complexes with alkenes. Kinetic and spectroscopic evidence for …

PN Becker, RG Bergman

Index: Becker, Paul N.; Bergman, Robert G. Journal of the American Chemical Society, 1983 , vol. 105, # 10 p. 2985 - 2995

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Citation Number: 48

Abstract

Results Thermal Exchange of Olefins in CpCo (dinitrosoa1kane) Complexes. Heating compound 1 with norbornene (2a) or substituted norbornene4 2b at temperatures between 45 and 85 OC in benzene-d, or toluene-d8 converted it quantitatively into 3a, b (eq 2) and 2, 3-dimethyl-2-butene.