Chemistry Letters

Michael-type additions to α, β-enoyliron (cyclopentadienyl) dicarbonyl complexes and its application to β-lactam synthesis

I Ojima, HB Kwon

Index: Ojima, Iwao; Kwon, Hyok Boong Chemistry Letters, 1985 , p. 1327 - 1330

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Citation Number: 5

Abstract

Michael-type additions of amines and thiols to α, β-enoyliron (cyclopentadienyl) dicarbonyl complexes were carried out to give the corresponding new β-aminoalkanoyl-and β- thioalkanoyliron complexes in good to excellent yields. A β-aminoalkanoyliron complex was treated with bromine in the presence of triethylamine to give the expected β-lactam in an excellent yield.

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