Coordination Abilities of Di??2??picolylphenylphosphane Judged on the Basis of Charge Density Investigations

…, F Engelhardt, R Herbst??Irmer, D Stalke

Index: Objartel, Ina; Leusser, Dirk; Engelhardt, Felix; Herbst-Irmer, Regine; Stalke, Dietmar Zeitschrift fur Anorganische und Allgemeine Chemie, 2013 , vol. 639, # 11 p. 2005 - 2012

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Abstract

Abstract The hindered reactivity of [PhP (CH 2 Py) 2 LiCl] 2 (2) compared to the coordination behavior of the lithium chloride free ligand PhP (CH 2 Py) 2 (Py= 2-pyridyl)(1) could be elucidated by means of experimental electron density studies. According to the successful synthesis of metal complexes containing the dianionic Janus Head ligand [PhP (CHPy) 2] 2– , the formation and the coordination pattern of the monoanionic ligand [PhP {C (H) Py}(CH ...