Tetrahedron Letters

Palladium dichloride catalyzed cope rearrangements of functionalized acyclic 1, 5-dienes

LE Overman, AF Renaldo

Index: Overman, Larry E.; Renaldo, Alfred F. Tetrahedron Letters, 1983 , vol. 24, # 35 p. 3757 - 3760

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Citation Number: 23

Abstract

Abstract The Cope rearrangement of acyclic 1, 5-dienes having an electron-withdrawing group at carbon-3 and an alkyl substituent at carbon-2 is effectively catalyzed by palladium dichloride. This reaction can be employed to achieve clean γ-allylation of vinyl esters and ...