In situ formation of vinylboranes for use in Diels Alder reactions. An easy one-pot Diels-Alder synthesis of cyclohexenols

DA Singleton, JP Martinez, GM Ndip

Index: Singleton, Daniel A.; Martinez, Jose P.; Ndip, Grace M. Journal of Organic Chemistry, 1992 , vol. 57, # 21 p. 5768 - 5771

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Citation Number: 48

Abstract

Recent reports from this laboratory have detailed the high reactivity and selectivity of vinylboranes as Diels-Alder dienophiles and have described the exceptional physical organic aspects of these reactions.'The major limitation on the utility and synthetic appeal of vinylboranes is the difficulty associated with manipdating these highly pyrophoric materials. This is particularly true of the highly volatile vinyldimethylborane, with which standard ...

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