Synthesis and characterisation of benzyl phosphino-thioether and-thiolato Pd (II) complexes and their applications in Suzuki coupling reactions

…, D Koursarou, L Ooi, PN Horton, MB Hursthouse

Index: Dervisi, Athanasia; Koursarou, Despina; Ooi, Li-Ling; Horton, Peter N.; Hursthouse, Michael B. Dalton Transactions, 2006 , # 48 p. 5717 - 5724

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Citation Number: 14

Abstract

The synthesis of the benzyl phosphinothioether derivatives Ph2PCH2CH (Et) SR and their corresponding palladium complexes are reported, where R= CH2Ph (3), R= CH2-3, 5-Me- C6H3 (4) and R= 1-CH2C10H7 (5). Crystallographic data obtained for the complexes Pd (3) Cl2 and Pd (4) Cl2 show intra-and inter-molecular π–π interactions between the aromatic rings on the P and S substituents, and NOE experiments for Pd (4) Cl2 show that these ...