Organometallics

Carbanions from. alpha.-phenylthio boronic esters as synthetic intermediates

DS Matteson, KH Arne

Index: Matteson, Donald S.; Arne, Karl H. Organometallics, 1982 , vol. 1, p. 280 - 288

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Citation Number: 30

Abstract

Carbanions stabilized by adjacent boron have recently been generated by deprotonation of sterically hindered organoboron compounds with hindered lithium dialkylamide P and show promise as intermediates for organic synthesis. Prior to these discoveries, boron-substituted carbanions were accessible only through deboronation of compounds having three or four boronic ester groups5p6 or two boronic ester and one or two group 4 metal substituents ...