Stereocontrolled synthesis of δ-hydroxy allylic phosphine oxides by allylic ester transposition

AB McElroy, S Warren

Index: McElroy, Andrew B.; Warren, Stuart Tetrahedron Letters, 1985 , vol. 26, # 13 p. 1677 - 1680

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Citation Number: 14

Abstract

Tetrahedron Letters,Vol.26,No.l3,pp 1677-1680,1985 ... Andrew B. McElroy and Stuart Warren* University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW. ... The title compounds (3) were synthesised by stereospecific [1,3] rearrangement, controlled by the Ph PO group, from single isomers of the Horner-Wittig a ducts ... We have recently reported' the synthesis of &hydroxy-allylic ... (3) as intermediates in the synthesis of diene alcohols.