Tetrahedron Letters

Copper iodide-catalyzed aziridination of alkenes with sulfonamides and sulfamate esters

JWW Chang, TMU Ton, Z Zhang, Y Xu, PWH Chan

Index: Chang, Joyce Wei Wei; Ton, Thi My Uyen; Zhang, Zhengyang; Xu, Yanjun; Chan, Philip Wai Hong Tetrahedron Letters, 2009 , vol. 50, # 2 p. 161 - 164

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Citation Number: 20

Abstract

An efficient copper iodide-catalyzed aziridination of a variety of alkenes with sulfonamides and sulfamate esters as the nitrogen source and iodosylbenzene (PhIO) as the oxidant is reported herein. The reaction is operationally straightforward, applicable to a variety of alkenes containing electron-withdrawing, electron-donating, and sterically encumbered substrate combinations, and proceeds under mild conditions at room temperature in good ...

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