The Journal of Organic Chemistry

Construction of a soluble heptacyclic terpyridine

TW Bell, A Firestone

Index: Bell, Thomas W.; Firestone, Albert Journal of Organic Chemistry, 1986 , vol. 51, # 5 p. 764 - 765

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Citation Number: 16

Abstract

Construction of a Soluble Heptacyclic Terpyridine Summary: A new synthesis of the quino[8,7-b][1,10]- phenanthroline nucleus is reported, allowing the intro- duction of solubilizing substituents and saturated terminal rings. ... Sir: The useful complexation properties of 2,2'-bipyridine and 2,2':6',2''-terpyridine have stimulated interest in higher polypyridine homologues.' Despite the utility of 1,lO- phenanthroline as a ligand,* synthetic difficulties have limited access to ...

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