Synthesis, structure and photoluminescence of two porous metal-organoboron frameworks with rtl topology

Y Liu, X Xu, WM Xuan, CF Zhu, Y Cui

Index: Liu, Yan; Xu, Xin; Xuan, WeiMin; Zhu, ChengFeng; Cui, Yong Science China Chemistry, 2011 , vol. 54, # 9 p. 1430 - 1435

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Abstract

Abstract Rigid trigonal tris (3-pyridylduryl) borane L was synthesized through four steps in good overall yield from readily available 1, 2, 4, 5-tetramethylbenzene and was used to construct two porous cadmium (II) complexes Cd (L) X 2· G (X= Cl, Br; G= guset molecules), 1 (Cd (L) Cl 2· EtOH· i PrOH· 3H 2 O) and 2 (Cd (L) Br 2· MeOH· C 7 H 8· 3H 2 O), under mild reaction conditions. 1 and 2 are isostructural and featured with 3D porous metal- ...