Synthesis and decomposition of the N-alkyl-N-nitro-O-benzoylhydroxylamines

…, J Reefer, RH Erickson, PM Dzadzic

Index: White, Emil H.; Reefer, John; Erickson, Ronald H.; Dzadzic, Petar M. Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4872 - 4876

Full Text: HTML

Citation Number: 11

Abstract

Nitration of N-alkyl-0-benzoylhydroxylamines yields the corresponding N-nitro derivatives. At modest temperatures these compounds decompose to yield alkyl benzoates, alkenes, benzoic acid, and nitrous oxide. In the caee of primary alkylnitrohydroxylamines, nitroalkanes and alkyl nitrates are also formed. The alkyl benzoates are products of ionic reactions since skeletal rearrangements characteristic of carbonium ions OCCUT. The ...

Related Articles:

Acid-catalyzed reactions of 2, 2, 2-trifluorodiazoethane for analysis of functional groups by fluorine-19 nuclear magnetic resonance spectrometry

[Koller, K. L.; Dorn, H. C. Analytical Chemistry, 1982 , vol. 54, # 3 p. 529 - 533]

Solvolytic reactions in fluorinated alcohols. Role of nucleophilic and other solvation effects

[Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659]

A Simple Method for Determination of Solvolysis Rates by 1H NMR

[Creary, Xavier; Jiang, Ziqi Journal of Organic Chemistry, 1994 , vol. 59, # 17 p. 5106 - 5108]

Solvolytic reactions in fluorinated alcohols. Role of nucleophilic and other solvation effects

[Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659]

Solvolytic reactions in fluorinated alcohols. Role of nucleophilic and other solvation effects

[Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659]

More Articles...