Highly branched molecules. V. Solvolysis of tertiary carbinyl p-nitrobenzoates from tri-tert-butyl to trineopentyl

PD Bartlett, TT Tidwell

Index: Bartlett,P.D.; Tidwell,T.T. Journal of the American Chemical Society, 1968 , vol. 90, p. 4421 - 4428

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Citation Number: 52

Abstract

Abstract: The first-order solvolysis rate constants for the p-nitrobenzoate esters of tri-t- butylcarbinol, di-tbutylneopentylcarbinol, t-butyldineopentylcarbinol, and trineopentylcarbinol relative to t-butyl p-nitrobenzoate in 60% dioxane (by weight) ...