Chemische Berichte

Über Thioacyl??isocyanate, XV. Reaktionen mit nucleophilen C??Verbindungen

J Goerdeler, ML Tiedt, K Nandi

Index: Goerdeler, Joachim; Tiedt, Marie-Louise; Nandi, Kumaresh Chemische Berichte, 1981 , vol. 114, # 8 p. 2713 - 2722

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Citation Number: 12

Abstract

Abstract Die Reaktion von Thioacyl-isocyanaten mit Natriummalonester und verwandten Verbindungen führt zu den Addukten 1, die teils als Amide, teils als tautomere Verbindungen vorliegen. Sie sind für weiter führende Synthesen, z. B. zu 2, 3, 4, geeignet.- Thiobenzoyl-isocyanat ergibt mit nucleophilen Alkenen und Alkinen alternativ ungesättigte Carbonamide (5, 6, 7), Cycloaddukte (8, 9, 12, 13, 15, 16) oder Cycloaddukte minus HX ( ...

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