Palladium??Catalyzed Carbonylation/Acyl Migratory Insertion Sequence

…, M Gong, X Zhao, Y Zhang, J Wang

Index: Zhang, Zhenhua; Liu, Yiyang; Gong, Mingxing; Zhao, Xiaokun; Zhang, Yan; Wang, Jianbo Angewandte Chemie - International Edition, 2010 , vol. 49, # 6 p. 1139 - 1142

Full Text: HTML

Citation Number: 89

Abstract

Migratory insertion is one of the fundamental processes in organopalladium chemistry. In particular, migratory insertion of a CO ligand and the formation of reactive acylpalladium intermediate is a powerful method for introducing a carbonyl functionality into organic molecules. The catalytic cycle involving such a key step has been developed into one of the most important tools to synthesize various carbonyl compounds.[1] However, for a long ...

Related Articles:

Gold??Catalyzed Homogeneous Oxidative Cross??Coupling Reactions

[Zhang, Guozhu; Peng, Yu; Cui, Li; Zhang, Liming Angewandte Chemie, International Edition, 2009 , vol. 48, # 17 p. 3112 - 3115]

Rh (I)-catalyzed CO gas-free carbonylative cyclization reactions of alkynes with 2-bromophenylboronic acids using formaldehyde

[Ku, Melih; Artok, Oezge Aksin; Ziyanak, Firat; Artok, Levent Synlett, 2008 , # 17 p. 2587 - 2592]

On the mechanism of the thermal conversion of cyclopropenyl-substituted oxazolinones to pyridines

[Padwa, Albert; Cohen, Leslie A.; Gingrich, Henry L. Journal of the American Chemical Society, 1984 , vol. 106, # 4 p. 1065 - 1073]

On the mechanism of the thermal conversion of cyclopropenyl-substituted oxazolinones to pyridines

[Padwa, Albert; Cohen, Leslie A.; Gingrich, Henry L. Journal of the American Chemical Society, 1984 , vol. 106, # 4 p. 1065 - 1073]

Iridium??Catalyzed Coupling Reaction of Primary Alcohols with 2??Alkynes Leading to Hydroacylation Products

[Hatanaka, Shintaro; Obora, Yasushi; Ishii, Yasutaka Chemistry - A European Journal, 2010 , vol. 16, # 6 p. 1883 - 1888]

More Articles...