Dynamics and energetics of the singlet-triplet interconversion of diphenylcarbene
KB Eisenthal, NJ Turro, M Aikawa…
Index: Eisenthal, K.B.; Turro, N.J.; Aikawa, M.; Butcher, J.A.; DuPuy, C.; et al. Journal of the American Chemical Society, 1980 , vol. 102, # 21 p. 6563 - 6565
Full Text: HTML
Citation Number: 69
Abstract
(IDPC) and triplet diphenylcarbene (3DPC), the ground state, exist in rapid equilibrium during most reactions (Scheme I). 2 A pioneering flash spectroscopic study of DPC by Closs and Rabinow'has supplied an estimate of the upper limit for the equilibrium constant; however, the absolute rate constants for interconversion of the spin states of DPC were not measured due to the ultrafast rate constant (kST) of the'DPC-'DPC process, which was ...
Related Articles:
[Ohta, Akihiro; Dahl, Klaus; Raab, Rainer; Geittner, Jochen; Huisgen, Rolf Helvetica Chimica Acta, 2008 , vol. 91, # 5 p. 783 - 804]
[Ohta, Akihiro; Dahl, Klaus; Raab, Rainer; Geittner, Jochen; Huisgen, Rolf Helvetica Chimica Acta, 2008 , vol. 91, # 5 p. 783 - 804]
[Ohta, Akihiro; Dahl, Klaus; Raab, Rainer; Geittner, Jochen; Huisgen, Rolf Helvetica Chimica Acta, 2008 , vol. 91, # 5 p. 783 - 804]
[Eisenthal, K. B.; Turro, N. J.; Sitzmann, E. V.; Gould, I. R.; Hefferon, G.; et al. Tetrahedron, 1985 , vol. 41, # 8 p. 1543 - 1554]
[Eisenthal, K. B.; Turro, N. J.; Sitzmann, E. V.; Gould, I. R.; Hefferon, G.; et al. Tetrahedron, 1985 , vol. 41, # 8 p. 1543 - 1554]