Reactions of α-aryl carbonyl compounds with lithium ester enolates

…, JAJ Geenevasen, H Cerfontain

Index: Veen, Reinhout H. van der; Geenevasen, Jan A. J.; Cerfontain, Hans Canadian Journal of Chemistry, 1984 , vol. 62, p. 2202 - 2205

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Citation Number: 2

Abstract

This report describes the synthesis of β-hydroxy esters in good yields by reaction of α-aryl substituted ketones and phenylethanal with lithium methyl acetate and derivatives as anionoid reagents. The incomplete substrate conversion is ascribed to the enolate formation of the α-aryl carbonyl compounds, which concurrent reaction is negligibly small with aliphatic carbonyl compounds. The conversion of β-tetralone with lithium methyl acetate ...

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