Journal of the American Chemical Society

The Photochemical Type II Process in 2-Hexanone-5, 5-d2 and 2-Hexanone1

R Srinivasan

Index: Srinivasan Journal of the American Chemical Society, 1959 , vol. 81, p. 5061,5063

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Citation Number: 36

Abstract

The photolysis of Z-hexanone-5, 5-d. st 3130. &. and room temperature was found to give mainly CaHsD and acetone which was a mixture of CH3COCH2D (457c) and CHsCOCH3 (54%). Since the course of the photolysis and the nature of the minor products were similar to that of 2-hexanone, it was surmised that acetone-& which may have been formed in the type I1 primary process, wa; subsequently exchanging the odd deuterium atom for a ...

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