1, 5-Asymmetric induction of chirality: diastereoselective addition of organoaluminium reagents and allylstannanes into aldehyde groups in the side-chain of π- …

SV Ley, LR Cox

Index: Ley, Steven V.; Burckhardt, Svenja; Cox, Liam R.; Meek, Graham Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 22 p. 3327 - 3337

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Citation Number: 17

Abstract

π-Allyltricarbonyliron lactone complex 5, bearing an aldehyde group in the side-chain, can be easily prepared from commercially available (2, 4 [][])-ethyl hexadienoate and reacts with organoaluminium and allylstannane nucleophiles to afford secondary alcohols. In analogy with the corresponding ketone-substituted compl