Resonance and the Hindered Carbonyl—Grignard Reaction. I

RT Arnold, H Bank, RW Liggett

Index: Arnold; Bank; Liggett Journal of the American Chemical Society, 1941 , vol. 63, p. 3444

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Abstract

3444 RT ARNOLD, HAROLD BANK AND R. W. LIGGBTT ... Assuming equilibrium to be nearly reached in those steps given as reversible, the rate law for this series of reactions is -d(Oz)/dt = k(CO2) (C~H602)(OH-)a'/”. By using the first ion CsH6- 02- in reaction 5 the mechanism is applicable to the autoxidation of catechol. The product of the reaction C6H6O4 or its ion ... [CONTRIBUTION FROM THE SCHOOL OF CHEMISTRY OF THE UNIVERStTY OF MINNESOTA] ...

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