Total synthesis of (±)-scopadulin

SMA Rahman, H Ohno, T Murata…

Index: Tomioka, Hiroki; Oshima, Koichiro; Nozaki, Hitoshi Tetrahedron Letters, 1982 , vol. 23, # 1 p. 99 - 100

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Citation Number: 14

Abstract

... Volume: Page: ... Strong NOE was observed between 6-H and 1'H. The facial selectivity was regulated by the axial methyl at C-10 and a ... Unlike the model study, 12 without deprotecting the TMS group, the nitrile 23 was exposed to excess LiAlH 4 at reflux, and the ...