(Thioallyl) iron tricarbonyl complexes by the reaction of allene episulfides with diiron nonacarbonyl

W Ando, N Choi, Y Kabe

Index: Ando, Wataru; Choi, Nami; Kabe, Yoshio Journal of the American Chemical Society, 1990 , vol. 112, # 11 p. 4574 - 4576

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Citation Number: 22

Abstract

2b 5 b stable yellow and orange crystalline materials with mp 59-60 OC and I 1 1.5-1 12.5 OC, respectively. The common fragments of C3SFe (CO), in 2a and 2b exhibit two distinct CO absorptions from 1950 to 2100 cm-'in the IR spectra and two or three sets of olefinic signals in the 13C NMR spectra. At room temperature, the carbonyl ligands at iron are fluxional in 2a with one broad carbonyl signal in I3C NMR but not in 2b as indicated by the ...

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