Synthesis, spectroscopy and structural characterization of silver (I) complexes containing unidentate N-donor azole-type ligands

F Marchetti, C Pettinari, R Pettinari, A Pizzabiocca…

Index: Effendy; Marchetti, Fabio; Pettinari, Claudio; Pettinari, Riccardo; Pizzabiocca, Adriano; Skelton, Brian W.; White, Allan H. Inorganica Chimica Acta, 2006 , vol. 359, # 5 p. 1504 - 1512

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Abstract

From the interaction between azole-type ligands L and AgX (X= NO3 or ClO4) or [AgX (PPh3) n](X= Cl, n= 3; X= MeSO3, n= 2), new ionic mononuclear [Ag (L) 2] X and [Ag (PPh3) 3L][X] or neutral mono-([Ag (PPh3) nL (X)]) or di-nuclear ([{Ag (PPh3)(L)(μ-X)} 2]) complexes have been obtained which have been characterized through elemental analysis, conductivity measurements, IR, 1H NMR and, in some cases, also by 31P {1H} NMR ...