Palladium (II)/copper halide/solvent combination for selective intramolecular domino reactions of indolecarboxylic acid allylamides: An Unprecedented arylation/ …

…, EM Beccalli, E Borsini, S Galli, G Lanza…

Index: Broggini, Gianluigi; Barbera, Vincenzina; Beccalli, Egle M.; Borsini, Elena; Galli, Simona; Lanza, Giuseppe; Zecchi, Gaetano Advanced Synthesis and Catalysis, 2012 , vol. 354, # 1 p. 159 - 170

Full Text: HTML

Citation Number: 35

Abstract

Abstract Intramolecular oxidative palladium-catalyzed reactions of indolylallylamides in the presence of the couple bis (acetonitrile) palladium dichloride and copper (II) halide are described. Starting from 2-and 3-indolylallylamides and involving in both cases the C-3 position of the indole nucleus, variously substituted β-carbolinones were obtained by arylation/halogenation, arylation/esterification or arylation/carboalkoxylation processes. ...

Related Articles:

Regioselective formation of six-and seven-membered ring by intramolecular Pd-catalyzed amination of N-allyl-anthranilamides

[Abbiati, Giorgio; Beccalli, Egle M.; Broggini, Gianluigi; Zoni, Caterina Journal of Organic Chemistry, 2003 , vol. 68, # 20 p. 7625 - 7628]

Uncommon intramolecular palladium-catalyzed cyclization of indole derivatives

[Beccalli, Egle M.; Broggini, Gianluigi Tetrahedron Letters, 2003 , vol. 44, # 9 p. 1919 - 1921]

More Articles...