Thioenamide photochemistry

A Couture, R Dubiez…

Index: Couture, Axel; Dubiez, Regine; Lablache-Combier, Alain Journal of the Chemical Society, Chemical Communications, 1982 , # 15 p. 842 - 843

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Abstract

In contrast with their oxo-analogues, thioenamides undergo photochemical cyclization to yield isoquinolinethione derivatives which are easily converted into isoquinolones and tetrahydroisoquinolines by treatment with benzeneseleninic anhydride and EtO3BF4– NaBH4, respectively.

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