Synthesis of biphenyl-based arsine ligands by Suzuki–Miyaura coupling and their application to Pd-catalyzed arsination
PM Uberman, MN Lanteri, SCP Puenzo…
Index: Uberman, Paula M.; Lanteri, Mario N.; Parajon Puenzo, Sol C.; Martin, Sandra E. Dalton Transactions, 2011 , vol. 40, # 36 p. 9229 - 9237
Full Text: HTML
Citation Number: 10
Abstract
A versatile and efficient approach for the synthesis of new biphenyl-based arsine ligands, by a Pd-catalyzed arsination to introduce the-AsPh2 moiety, and then a Suzuki–Miyaura cross- coupling for biaryl construction is reported. By Pd-catalyzed arsination with n-Bu3SnAsPh2 (1),(2-bromophenyl) diphenylarsine (2, 83%) was obtained. The Suzuki–Miyaura reaction between the bromoarsine 2 and aryl boronic acids bearing different substituents provided ...
Related Articles:
[Gillespie, Donal G.; Walker, Brian J.; Stevens, David; McAuliffe, Charles A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1697 - 1703]
[Gillespie, Donal G.; Walker, Brian J.; Stevens, David; McAuliffe, Charles A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1697 - 1703]
[Gillespie, Donal G.; Walker, Brian J.; Stevens, David; McAuliffe, Charles A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1697 - 1703]
[Gillespie, Donal G.; Walker, Brian J.; Stevens, David; McAuliffe, Charles A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1697 - 1703]
[Gillespie, Donal G.; Walker, Brian J.; Stevens, David; McAuliffe, Charles A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 8 p. 1697 - 1703]