Selenium catalysed oxidations with aqueous hydrogen peroxide. Part 3: Oxidation of carbonyl compounds under mono/bi/triphasic conditions

GJ ten Brink, JM Vis, IWCE Arends, RA Sheldon

Index: Ten Brink, Gerd-Jan; Vis, J.Martijn; Arends, Isabel W.C.E; Sheldon, Roger A Tetrahedron, 2002 , vol. 58, # 20 p. 3977 - 3983

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Citation Number: 87

Abstract

The total synthesis of 3, 5-bis (perfluorooctyl) phenyl butylselenide (1), a recyclable catalyst for oxidation reactions with hydrogen peroxide, is described. The catalyst can be used for oxidation of aldehydes and ketones under monophasic, but also fluorous biphasic or fluorous triphasic conditions.