Journal of the American Chemical Society

The Aluminum Chloride-Catalyzed Addition of t-Butyl Chloride to Propylene

VA Miller

Index: Miller Journal of the American Chemical Society, 1947 , vol. 69, p. 1765

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Citation Number: 6

Abstract

Summary Molecular weights of bottle-polymerized GR-S have been determined as functions of conversion. The partial conversion molecular weights are found to be negative between 61 and 74% conversion, thus indicating? net decrease in the number of polymer molecules with increasing weight conversion. This negative rate of molecule formation is attributed to intermolecular cross-linking. Above 74% conversion intramolecular cro3s-linking and ...