Journal of Catalysis

Nickel–Magnesia Catalysts: An Alternative for the Hydrogenation of 1, 6-Hexanedinitrile

…, P Salagre, Y Cesteros, F Medina, JE Sueiras

Index: Salagre; Medina; Serra; Sueiras; Cesteros Journal of Catalysis, 2002 , vol. 209, # 1 p. 202 - 209

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Citation Number: 25

Abstract

Two Ni–MgO systems were synthesized and characterized as nickel catalysts for the hydrogenation of 1, 6-hexanedinitrile (adiponitrile) in the gas phase. The activity results were compared with those obtained for a commercial Raney–Ni. All three catalysts showed high selectivity to 1, 6-hexanediamine, for a total conversion with a maximum of 96% for the Ni–MgO catalyst, which was made from a NiO–MgO solution. However, only Ni–MgO ...

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