Bulletin des Sociétés Chimiques Belges

The unusual rearrangement of N??nitroso??N, O??dibenzylhydroxylamines with acetic anhydride

K Kano, JP Anselme

Index: Kano, Kunio; Anselme, Jean-Pierre Bulletin des Societes Chimiques Belges, 1983 , vol. 92, # 3 p. 229 - 232

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Abstract

Abstract Treatment of N-nitroso-N, O-dibenzylhydroxylamine (2a) with acetic anhydride in benzene at reflux results in a remarkable rearrangement to 2-benzoyl-1- acetylbenzylhydrazine and it was established that it is the N-benzyl substituent of 2a that is transformed into the benzoyl group of the rearranged product (3a).