Reactivity of Hydroxy??and Aquo (hydroxy)?螃?3??iodane–Crown Ether Complexes

…, Y Yokota, T Suefuji, K Yamaguchi…

Index: Miyamoto, Kazunori; Yokota, Yukie; Suefuji, Takashi; Yamaguchi, Kentaro; Ozawa, Tomoyuki; Ochiai, Masahito Chemistry - A European Journal, 2014 , vol. 20, # 18 p. 5447 - 5453

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Citation Number: 7

Abstract

Abstract We have designed a series of hydroxy (aryl)-λ 3-iodane–[18] crown-6 complexes, prepared from the corresponding iodosylbenzene derivatives and superacids in the presence of [18] crown-6, and have investigated their reactivities in aqueous media. These activated iodosylbenzene monomers are all non-hygroscopic shelf-storable reagents, but they maintain high oxidizing ability in water. The complexes are effective for the oxidation ...