The Journal of Organic Chemistry

Chemistry of the adducts of N, N'-diphenylformamidine with oxalyl chloride and phosgene

EA Barsa, R Richter

Index: Barsa, E. A.; Richter, R. Journal of Organic Chemistry, 1986 ,  vol. 51,  # 23  p. 4483 - 4485

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Citation Number: 8

Abstract

Reactions of N-substituted carboxylic acid amides with acylating agents such as acyl halides, phosphoryl chloride, thionyl chloride, and phosgene have been investigated in detail; the adduct formation between N, N-disubstituted formamides and POCl:, has become the basis of the widely used Vilsmeyer-Haack synthesis of aldehydes.'Only few reactions involving substrates containing a C= N bond and acylating agents have been reported. 2 ...