Allylbarium reagents: unprecedented regio-and stereoselective allylation reactions of carbonyl compounds

A Yanagisawa, S Habaue, K Yasue…

Index: Yanagisawa, Akira; Habaue, Shigeki; Yasue, Katsutaka; Yamamoto, Hisashi Journal of the American Chemical Society, 1994 , vol. 116, # 14 p. 6130 - 6141

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Citation Number: 144

Abstract

Abstract: The first direct preparation of allylbarium reagents by reaction of in situ generated reactive barium with various allylic chlorides and their new and unexpected selective allylation reactions with carbonyl compounds are disclosed. Highly reactive barium was readily prepared by the reduction of barium iodide with 2 equiv of lithium biphenylide in dry THF at room temperature. Avariety of carbonyl compounds reacted with barium reagents ...

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