Synthesis, structure and metal compounds of a novel chromophoric cyanamide ligand

CJ Adams

Index: Adams, Christopher J. Journal of the Chemical Society - Dalton Transactions, 1999 , # 12 p. 2059 - 2064

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Abstract

The novel compound 2-cyanaminofluoren-9-one (HL) has been synthesized, and is readily deprotonated to form the corresponding cyanamide anion L. This has been isolated as the TlL and AsPhL salts. The UV/visible spectra of HL and AsPhL show the same amine to carbonyl charge transfer transition seen in other aminofluo