Unusual transformations of the PhSiFCl group

SV Basenko, MG Voronkov, LE Zelenkov, AI Albanov

Index: Basenko; Voronkov; Zelenkov; Albanov Doklady Chemistry, 2009 , vol. 428, # 1 p. 210 - 212

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Citation Number: 2

Abstract

The reaction of equimolar amounts of OMTS and PhSiF2Cl (I) at 25 С initially proceeds similarly to reaction (7)(reaction (8)); however, another process is observed after about 24 h that results in 1, 1, 1 trime thyl 3 phenyl 3, 3 difluorodisiloxane and pentame thylchlorodisiloxane (reaction (9)).