Perfluoroalkylphosphine coordination chemistry of platinum: synthesis of (C 2 F 5) 2 PPh and (C 2 F 5) PPh 2 complexes of platinum (II)
JD Palcic, PN Kapoor, DM Roddick, RG Peters
Index: Palcic, Jason D.; Kapoor; Roddick, Dean M.; Peters, R. Gregory Dalton Transactions, 2004 , # 10 p. 1644 - 1647
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Citation Number: 7
Abstract
A 1∶ 1 addition of Ph2PCl to an ethereal solution of C2F5Li (formed from the reaction of BuLi with C2F5Cl) yields Ph2P (C2F5)(abbreviated pfepp)(1). The introduction of a fluoroethyl group results in a phosphine with electronic characteristics that approximate phosphites, bridging the electronic gap between traditional donor phosphine ligands and more electrophilic phosphine ligands like PhP (C2F5) 2 (2). The pfepp ligand 1 is isolated ...
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