Further study of estertin trichlorides, Cl 3 SnCH 2 CH 2 CO 2 R. Lewis acidity towards acetonitrile. Crystal structure of Cl 3 SnCH 2 CH 2 CO 2 Pr-i

RA Howie, ES Paterson, JL Wardell…

Index: Howie, R. Alan; Paterson, Eric S.; Wardell, James L.; Burley, Joseph W. Journal of Organometallic Chemistry, 1986 , vol. 304, p. 301 - 308

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Citation Number: 48

Abstract

Abstract Crystals of Cl 3 SnCH 2 CH 2 CO 2 Pri-i are orthorhombic, space group P2 1 2 1 2 1 with a 9.638 (6), b 10.004 (7) and c 12.848 (8) Å. The tin atom is five-coordinate with two chlorines and carbon equatorial and the remaining chlorine and the carbonyl oxygen axial, in a distorted trigonal-bipyramidal arrangement:(Sn Cl) ax 2.389 (3), average (Sn Cl) eq 2.320 (2), Sn C 2.142 (9), Sn O 2.337 (5) Å. Apart from the equatorial chlorine and the ...

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