Tetrahedron letters

Synthesis of 5-substituted 4-O-methyl tetramates

RCF Jones, AD Bates

Index: Jones, Raymond C.F; Bates, Andrew D. Tetrahedron Letters, 1986 , vol. 27, # 43 p. 5285 - 5288

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Citation Number: 30

Abstract

As part of an on-going programme of synthesis directed towards the 3-acyltetramic acids (I), the heterocyclic nucleus common to family of natural metabolites found in microorganisms and having a range of biological properties: we have previously reported the metallation of 4- methoxy-I-alkyl-A3-pyrrolin-2-ones (4-g-methyl tetramates; 2) to form the vinyl- lithiums(3).'Reaction of (3) with aldehydes is the basis of an acylation sequence at C-3. In ...

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