Journal of the American Chemical Society

Mo-catalyzed regio-, diastereo-, and enantioselective allylic alkylation of 3-aryloxindoles

BM Trost, Y Zhang

Index: Trost, Barry M.; Zhang, Yong Journal of the American Chemical Society, 2007 , vol. 129, # 47 p. 14548 - 14549

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Citation Number: 130

Abstract

A highly regio-, diastereo-, and enantioselective allylic alkylation reaction mediated by a chiral molybdenum catalyst has been developed as a novel entry into synthetically versatile 3-alkyl-3-aryloxindoles. Extremely bulky nucleophiles were employed to form a quaternary ...

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