Catalytic Dihydroxylation of Olefins with Hydrogen Peroxide: An Organic??Solvent??and Metal??Free System

Y Usui, K Sato, M Tanaka

Index: Usui, Yoko; Sato, Kazuhiko; Tanaka, Masato Angewandte Chemie - International Edition, 2003 , vol. 42, # 45 p. 5623 - 5625

Full Text: HTML

Citation Number: 131

Abstract

1, 2-Diols are widely used as intermediates in the perfume and fragrance industry, for the manufacture of cosmetics, for the synthesis of commercial products such as photographic materials and lubricants, and in drugs and foods.[1] Dihydroxylation of olefins is a straightforward method for the synthesis of 1, 2-diols, and various oxidants are now used for this purpose both in the laboratory and in industry.[2] The syn dihydroxylation of olefins is ...

Related Articles:

Diastereoselective inter-and intramolecular pinacol coupling of aldehydes promoted by monomeric titanocene (III) complex Cp2TiPh

[Yamamoto; Hattori; Miwa; Nakagai; Kubota; Okamoto; Itoh Journal of Organic Chemistry, 2001 , vol. 66, # 11 p. 3865 - 3870]

Alkene cis-dihydroxylation by [(Me3tacn)(CF3CO2) RuVIO2] ClO4 (Me3tacn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane): Structural characterization of [3+ 2] …

[Journal of the American Chemical Society, , vol. 127, # 41 p. 14239 - 14249]

An O-Xylyl Diol Protecting Group

[Poss, A. J.; Smyth, M. S. Synthetic Communications, 1989 , vol. 19, # 19 p. 3363 - 3366]

NaIO4/LiBr-mediated diastereoselective dihydroxylation of olefins: A catalytic approach to the prevost-woodward reaction

[Emmanuvel, Lourdusamy; Ali Shaikh, Tanveer Mahammad; Sudalai, Arumugam Organic Letters, 2005 , vol. 7, # 22 p. 5071 - 5074]

The Use of Bismuth (III) Acetate in'Wet'and'Dry'Prevost Reactions

[Trainor, Robert W.; Deacon, Glen B.; Jackson, W. Roy; Giunta, Nunzio Australian Journal of Chemistry, 1992 , vol. 45, # 8 p. 1265 - 1280]

More Articles...