Synthesis, Structural Characterization, Reactivity, and Catalytic Properties of Copper (I) Complexes with a Series of Tetradentate Tripodal Tris (pyrazolylmethyl) amine …

…, A Prieto, E Álvarez, C Maya, MC Nicasio…

Index: Haldon, Estela; Alvarez, Eleuterio; Nicasio, M. Carmen; Perez, Pedro J. Inorganic Chemistry, 2012 , vol. 51, # 15 p. 8298 - 8306

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Citation Number: 9

Abstract

A series of cationic and neutral copper (I) complexes with tris (pyrazolylmethyl) amine ligands (Tpa x) have been prepared and characterized. The structures in the solid state reveal their polynuclear nature and a μ2: κ2: κ1-coordination mode for the Tpa x ligands, whereas NMR studies agree with the existence of fluxional behavior in solution.

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